✦ LIBER ✦

Redox-Switched Exciton-Coupled Circular Dichroism: A Novel Strategy for Binary Molecular Switching

✍ Scribed by Steffen Zahn; James W. Canary

Book ID: 101300305
Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 101 KB
Volume: 37
Category: Article
ISSN: 0044-8249
DOI: 10.1002/(sici)1521-3773(19980216)37:3<305::aid-anie305>3.0.co;2-t

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✦ Synopsis

Intense chiroptical properties and efficient reversibility of the chemical redox cycle support the adaptability of the Cu /Cu complex system 1/2 for the development of a binary molecular device. Reduction proceeds with ascorbic acid, and oxidation with ammonium persulfate.