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Redox reactions of metal ions—III: Electronic rearrangements in the precursor bridged complex of the chromium(III)-chromium(II) exchange reactions

✍ Scribed by G.St. Nikolov


Book ID
118910261
Publisher
Elsevier Science
Year
1974
Weight
289 KB
Volume
36
Category
Article
ISSN
0022-1902

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Ultraviolet excitations of polypyridyl chromium-(III) complexes in alcoholic or aqueous alkaline media have been found to result in formation of chromium(B) complexes apparently in competition with formation of the thermally equilibrated 'E chromium(III) excited state. The upper state process probab