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Redox reactions of mercury derivatives of 8-alkylquinolines with Pd(0) and Pt(0) complexes

✍ Scribed by V. V. Bashilov; É. V. Maskaeva; A. A. Musaev; V. I. Sokolov; O. A. Reutov

Book ID
112446428
Publisher
Springer
Year
1984
Tongue
English
Weight
437 KB
Volume
33
Category
Article
ISSN
1573-9171

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## Abstract Reactions of 1,2,4‐trithiolanes with Pt^0^ complexes often proceed via an oxidative addition of the Pt^0^ complex fragment into the S–S bond and subsequent extrusion of a thioketone molecule by ring contraction. The six‐membered intermediate **5a**, formed in the course of the reaction