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Redox reaction of μ−O in water determined by the chemical shift

✍ Scribed by K. Nishiyama; T. Azuma; W. K. Dawson; A. Matsushita

Book ID
112685418
Publisher
Springer
Year
1994
Tongue
English
Weight
313 KB
Volume
87
Category
Article
ISSN
0304-3843

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Shift of the rate-determining step in a
Shift of the rate-determining step in a consecutive chemical reaction with variation of the reaction affinity
✍ M. Enyo 📂 Article 📅 1975 🏛 John Wiley and Sons 🌐 English ⚖ 355 KB

## Abstract A consecutive single‐route reaction is considered. When two (groups of) steps compete in controlling the overall reaction rate, there exists a general rule that the earlier step in the flow of the overall reaction tends to be rate‐determining with the increase of the reaction affinity.