Redox potential and electrocatalysis of O2 reduction on transition metal chelates
β Scribed by A. van der Putten; A. Elzing; W. Visscher; E. Barendrecht
- Publisher
- Elsevier Science
- Year
- 1987
- Weight
- 611 KB
- Volume
- 221
- Category
- Article
- ISSN
- 0022-0728
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Abatnet -The cathode process of oxygen reduction on thiospinels and other sulphida was examined by potentiodynamic, galvanostatic and rotating ring-disc electrode measurements. The highest activity was found with the sulphur compounds of cobalt and iron. The results are compared with those obtained
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It was found that during the electrochemical reduction of molecular oxygen in acidic medium the ternary cluster materials (M,Mo,S, ; M: Ag, Ba, Cd, Zn, Sn, Pb, In) produce 4% H,O, and the Pd-containing cluster material produces 8% H,O, when their surface is free from oxides. Since, eg, Ag metal prod