Redox Intermediates of Plant and Mammalian Peroxidases: A Comparative Transient-Kinetic Study of Their Reactivity Toward Indole Derivatives

A Solid-State, Solution, and Theoretical

A Solid-State, Solution, and Theoretical Structural Study of Kinetic and Thermodynamic Lithiated Derivatives of a Simple Diazomethane and Their Reactivities Towards Aryl Isothiocyanates

✍ David R. Armstrong; Robert P. Davies; Robert Haigh; Mark A. Hendy; Paul R. Raith 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 252 KB

## Abstract (Trimethylsilyl)diazomethane (**1‐H**) reacts with __n__BuLi in THF at elevated temperature to afford (previously reported) **1‐Li·^3^/~2~THF**. However, reaction in hexane/TMEDA at low temperature affords instead the __N__‐lithiate Me~3~SiCNNLi·TMEDA (**9**), which is a novel “open” ps