Redox initiation of bulk thiol–ene polymerizations
✍ Scribed by Cole, Megan A. ;Jankousky, Katherine C. ;Bowman, Christopher N.
- Book ID
- 118038868
- Publisher
- The Royal Society of Chemistry
- Year
- 2013
- Tongue
- English
- Weight
- 597 KB
- Volume
- 4
- Category
- Article
- ISSN
- 1759-9954
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## Abstract Thermally and photochemically initiated thiol–ene click reactions using thiol‐ and allyl‐ end functionalized linear polystyrenes with various enes (allyl bromide, methyl acrylate, and methyl methacrylate) and thiol (3‐mercaptopropionic acid) have been investigated. Allyl‐ and thiol‐end‐
## Abstract The laser‐initiated polymerization of a thiol‐ene photopolymerizable system was studied. The laser was operated in single‐ and multiple‐pulse modes to generate exotherms, which were measured in a modified differential scanning calorimeter. Arrhenius plots of the polymerization, obtained