Redox comparisons of pseudotetrahedral copper(I) complexes containing tripod ligands
β Scribed by Kenneth D. Karlin; Suzanne E. Sherman
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 215 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0020-1693
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## Abstract A series of pseudoβtetrahedral copper(I) complexes carrying bis(imino)acenaphthene (BIAN) ligands as acceptor subunits and various phosphane derivatives was prepared and characterized by elemental analysis, Xβray crystallography and spectroscopic techniques. The electronic spectra of th
Complex formation and redox reactions between copper (II) ion and D-penicillamine were studied in detail as functions of the metal/-ligand ratio and the concentration of halide ions. It was established that a copper (I)- D-penicillamine polymeric complex of amphoteric character is formed when excess