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Redox chemistry of Pd2+, Pt2+, Rh3+–TPPTS systems in water: pH influence on the preparation of low valent TPPTS complexes

✍ Scribed by E.G. Kuntz; O.M. Vittori


Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
159 KB
Volume
129
Category
Article
ISSN
1381-1169

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✦ Synopsis


Ž

. Ž . The redox process of the water-soluble systems: TPPTS-Pd OAc , PdSO , PtCl , Rh SO , and RhCl , have been 2 4 2 2 43 3 31 Ž .

Ž . observed, implies that the different hydroxochloro Rh III species react directly with TPPTS to produce OTPPTS and Rh I which is subsequently complexed by TPPTS. q 1998 Elsevier Science B.V.