✦ LIBER ✦

Redox behavior of the electronically unsaturated osmium clusters Os3(.mu.-H)2(CO)9L and their saturated congeners Os3(.mu.-H)(H)(CO)10L (L = CO, PPh3, AsPh3)

✍ Scribed by Osella, Domenico.; Stein, Edison.; Nervi, Carlo.; Zanello, Piero.; Laschi, Franco.; Cinquantini, Arnaldo.; Rosenberg, Edward.; Fiedler, Jan.

Book ID: 127297948
Publisher: American Chemical Society
Year: 1991
Tongue: English
Weight: 626 KB
Volume: 10
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om00052a045

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Kinetics of intramolecular interconversi

Kinetics of intramolecular interconversion of two isomers of (.mu.-H)M3(.mu.-CNMe2)(CO)9L (M = Ru, L = PR3, AsPh3, or SbPh3; M = Os, L = AsPh3)

✍ Shaffer, Mark R.; Keister, Jerome B. 📂 Article 📅 1986 🏛 American Chemical Society 🌐 English ⚖ 797 KB

Preparation of (.mu.-H)3Os3(CO)9(.mu.3-C

Preparation of (.mu.-H)3Os3(CO)9(.mu.3-C)(B5H8) and (.mu.3-H)3Os3(CO)9(.mu.3-C)(C2B10H11): "alkylation" of pentaborane(9) and 1,2-dicarbadodecaborane by a triosmium methylidyne cluster

✍ Wermer, Joseph R.; Jan, Deng Yang; Getman, Thomas D.; Moher, Eric; Shore, Sheldo 📂 Article 📅 1988 🏛 American Chemical Society 🌐 English ⚖ 736 KB

Structural studies on polynuclear osmium

Structural studies on polynuclear osmium carbonyl hydrides. 16. Crystal structure of (.mu.-H)(.mu.-OMe)Os3(CO)10 and a comparison of the hinged Os(.mu.-H)2Os, Os(.mu.-H)(.mu.-OMe)Os, and Os(.mu.-OMe)2Os bridges in trinuclear (.mu.-H)n(.mu.-OMe)2-nOs3(CO)10 (n = 0-2) complexes

✍ Churchill, Melvyn Rowen; Wasserman, Harvey J. 📂 Article 📅 1980 🏛 American Chemical Society 🌐 English ⚖ 676 KB

The first measurements of activation vol

The first measurements of activation volumes for hydride fluxionality on metal clusters. Intramolecular exchange of hydrides on osmium and ruthenium complexes, H(.mu.-H)Os3(CO)10(PPh3) and (.mu.-H)2Ru3(.mu.3-CHCO2Me)(CO)9

✍ Keister, Jerome B.; Frey, Urban.; Zbinden, Donald.; Merbach, Andre E. 📂 Article 📅 1991 🏛 American Chemical Society 🌐 English ⚖ 616 KB

Structural studies on polynuclear osmium

Structural studies on polynuclear osmium carbonyl hydrides. 24. Crystal structures of the 60-electron cluster (.mu.-H)3Os3Ni(CO)9(.eta.5-C5H5) and the 59-electron radical cluster (.mu.-H)3Os3Co(CO)9(.eta.5-C5H5)

✍ Churchill, Melvyn Rowen; Bueno, Clifford 📂 Article 📅 1983 🏛 American Chemical Society 🌐 English ⚖ 733 KB

Synthesis, structure, and fluxional prop

Synthesis, structure, and fluxional properties of Os3H3(CO)9(SiPh3), a compound with the formally unsaturated Os(.mu.-H)2Os unit

✍ Willis, Anthony C.; Einstein, Frederick W. B.; Ramadan, Ramadan M.; Pomeroy, Rol 📂 Article 📅 1983 🏛 American Chemical Society 🌐 English ⚖ 299 KB