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Redistribution and Reduction Reactions of Alkoxysilanes

✍ Scribed by Ryan, John W.


Book ID
126902272
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
700 KB
Volume
84
Category
Article
ISSN
0002-7863

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The Birch reduction of (2 -trialkysilyl)furan-3-carboxylic acids has been applied to the synthesis of methyl (2-trialkylsilyl)tetrahydrofuran-3-carboxylates. It is believed that the silicon moiety in such substrates controls the sense of asymmetric induction observed in Michael reactions of the deri