Redetermination of tris(ethyl carbazate-κ2N,O)cobalt(II) dinitrate
✍ Scribed by Srinivasan, Krishnan ;Govindarajan, Subbaiah ;Harrison, William T. A.
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 934 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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The structure of the title complex, [Co(C 8 H 7 O 3 ) 2 (H 2 O) 2 ], has been redetermined in the space group C2/c. The original report [Xiao, Lan, Zhang & Jiang (2002). Guangxi Shifan Daxue Xuebao Ziran Kexueban (J. Guangxi Normal Univ.), 20, 81-83] declared the space group to be Cc. The molecule l
Single-crystal X-ray study T = 294 K Mean '(C±C) = 0.005 A Ê Disorder in solvent or counterion R factor = 0.030 wR factor = 0.071 Data-to-parameter ratio = 14.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 297 K Mean '(C±C) = 0.003 A Ê R factor = 0.024 wR factor = 0.068 Data-to-parameter ratio = 15.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, [Co(C~2~H~4~NO~2~)~3~], is a mononuclear cobalt(III) complex. The Co^III^ atom is six-coordinated by three N atoms and three O atoms from three chelating glycinate ligands, forming a slightly distorted octahedral configuration. In the crystal structure, the molecules are linked t