Redetermination of potassium chlorochromate, KCrO3Cl
✍ Scribed by Kolitsch, Uwe
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 369 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
KCrO 3 Cl, potassium trioxochlorochromate(VI), has been redetermined from room-temperature single-crystal X-ray data. The Cr atom is tetrahedrally coordinated by three O atoms (average CrÐO bond length 1.597 A Ê ) and one Cl atom at 2.1916 (8) A Ê , with nearly ideal tetrahedral angles. The K ion is coordinated by eight O and three Cl atoms. Isolated CrO 3 Cl tetrahedra and K ions are connected via common ligands. All atoms are in general positions.
📜 SIMILAR VOLUMES
In the title compound, C 7 H 4 ClNO 4 , the molecules form centrosymmetric dimers through OÐHÁ Á ÁO hydrogen bonds. The dimers are connected by CÐHÁ Á ÁO hydrogen bonds to form molecular tapes. Disorder of the H atom in the OÐ HÁ Á ÁO hydrogen bond is suggested.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.014 A Ê R factor = 0.082 wR factor = 0.253 Data-to-parameter ratio = 15.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.