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Recycling of spent hydroprocessing catalysts: EURECAT technology

โœ Scribed by G. Berrebi; P. Dufresne; Y. Jacquier


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
483 KB
Volume
10
Category
Article
ISSN
0921-3449

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โœฆ Synopsis


Disposal of spent catalyst is a growing concern for all refiners. Environmental regulations are becoming stricter and stricter and there are State recommendations to develop disposal routes which would emphasize recycling as much as possible, and processing the wastes as near as possible to the production center. In this context, EURECAT has developed a recycling process for the hydroprocessing catalysts used in the oil refineries (NiMo, CoMo, NiW on alumina or mixed alumina silica). The process starts with a regeneration of the catalyst to eliminate hydrocarbons, carbon and sulfur. After a caustic roasting, the material is leached to obtain a solution containing mainly molybdenum (or tungsten) and vanadium, and a solid containing essentially alumina, cobalt and/or nickel. Molybdenum and vanadium are separated by an ion exchange resin technique. The solid is processed in an arc furnace to separate the alumina. Nickel and cobalt are separated by conventional solvent extraction to obtain pure metal. Alumina is disposed of as an inert slag. The strength of the process lies in the combination of proven technologies applied by companies whose reliability in their respective field is well known. The aspects concerning spent catalyst handling, packaging and transport are also discussed.


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In recent years, increasing emphasis has been placed on recycling spent hydroprocessing catalysts due to environmental regulations which list them as hazardous waste materials. In the present work, the recycling of spent residue hydroprocessing catalysts that contained high levels of vanadium was in