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Reconstitution of the water-oxidizing complex in manganese-depleted photosystem II preparations using synthetic Mn complexes: a fluorine-19

โœ Scribed by Toshi Nagata; Sergei K. Zharmukhamedov; Andrei A. Khorobrykh; Vyacheslav V. Klimov; Suleyman I. Allakhverdiev


Publisher
Springer
Year
2008
Tongue
English
Weight
451 KB
Volume
98
Category
Article
ISSN
0166-8595

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Toward the Assignment of the Manganese O
โœ Dr. Adrian R. Jaszewski; Dr. Simon Petrie; Prof. Ronald J. Pace; Prof. Rob Stran ๐Ÿ“‚ Article ๐Ÿ“… 2011 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 592 KB

Density functional theory (DFT) and time-dependent DFT (TDDFT) calculations are reported on three sets of isomeric models of the {Mn(4)/Ca} water-oxidizing complex of photosystem II (PS II), which share the general formula [CaMn(4)O(4)(N(2)C(3)H(4))(RCOO)(6)](q)โ‹…(H(2)O)(n) (R=H, CH(3); q=-1, 0, +1,