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Reconciliation of calorimetrically and spectroscopically derived standard entropies for the six dimethylpyridines between the temperatures 250 K and 650 K: a stringent test of thermodynamic consistency

✍ Scribed by R.D. Chirico; T.D. Klots; S.E. Knipmeyer; A. Nguyen; W.V. Steele

Publisher: Elsevier Science
Year: 1998
Tongue: English
Weight: 396 KB
Volume: 30
Category: Article
ISSN: 0021-9614
DOI: 10.1006/jcht.1997.0327

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✦ Synopsis

Reconciliation of standard entropies ⌬ S cal derived from calorimetric and thermophysical 0 m T T Ž . property studies with standard entropies ⌬ S stat derived with assigned vibrational spectra 0 m

and the methods of statistical mechanics is used to demonstrate consistency between Ž thermophysical properties for the six dimethylpyridines Chemical Abstracts registry numbers:

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