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Recherches sur la formation et la transformation de dérivés organiques du fluor II. Sur la synthèse et l'estérification d'amino-alcools fluorés

✍ Scribed by Emile Cherbuliez; A. Yazgi; J. Rabinowitz


Publisher
John Wiley and Sons
Year
1960
Tongue
German
Weight
574 KB
Volume
43
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

The syntheses of monofluorinated amino‐alcohols (with primary, secondary and tertiary amino groups and also with quaternary ammonium groups) and of their phosphoric and acetic esters are described.


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Recherches sur la formation et la transf
✍ Emile Cherbuliez; Br. Baehler; G. Cordahi; F. Hunkeler; H. Probst; A. de Picciot 📂 Article 📅 1960 🏛 John Wiley and Sons 🌐 German ⚖ 524 KB

## Abstract Some new fluorinated phosphoric esters are described. The rate of hydrolysis of the organic fluorine and of the phosphoric ester bond is studied. The phosphoric ester group has a stabilizing effect on the fluorine in alkaline medium, whereas the fluorine has a labilizing effect on the p

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✍ Emile Cherbuliez; Br. Baehler; A. R. Sussmann; J. Rabinowitz 📂 Article 📅 1961 🏛 John Wiley and Sons 🌐 German ⚖ 256 KB 👁 1 views

3,3‐dimethylpentane‐2,4‐diol, a new diol, and its dicarbamate have been prepared. Some N,N‐diethylcarbamates of diols have also been prepared from N,N‐diethylcarbamoyl chloride and the corresponding diols.

Recherches sur la formation et la transf
✍ Emile Cherbuliez; Br. Baehler; A. Yazgi; J. Rabinowitz 📂 Article 📅 1961 🏛 John Wiley and Sons 🌐 German ⚖ 178 KB 👁 1 views

Some new diethylcarbamates of dialkylamino‐alcohols of type I (fluorinated or not) have been prepared from diethylcarbamylchloride and the corresponding aminoalcohols.

Recherches sur la formation et la transf
✍ Emile Cherbuliez; A. Yazgi; J. Rabinowitz 📂 Article 📅 1960 🏛 John Wiley and Sons 🌐 German ⚖ 302 KB

## Abstract The synthesis of some esters of 1‐diethylamino‐3‐fluoro‐propan‐2‐olis described. The nitrobenzoic ester is transformed with very good yield into the corresponding aminobenzoic ester by reduction with Sn and HC1 or by catalytic hydrogenation.

Recherches sur la formation et la transf
✍ Emile Cherbuliez; A. de Picciotto; J. Rabinowitz 📂 Article 📅 1960 🏛 John Wiley and Sons 🌐 German ⚖ 431 KB 👁 1 views

## Abstract Some new fluorinated hydroxy‐acids and hydroxy‐ethers as well as their phosphorylated derivatives are described.

Recherches sur la formation et la transf
✍ Emile Cherbuliez; Br. Baehler; A. R. Sussmann; J. Rabinowitz 📂 Article 📅 1960 🏛 John Wiley and Sons 🌐 German ⚖ 275 KB 👁 1 views

## Abstract The synthesis of 1‐fluoro‐4,4‐di‐hydroxymethyl‐pentane (I) and its dicarbamate (II) is described. (I) is obtained by classical alkylation of methylmalonic ester with 1‐ bromo‐3‐fluoro‐propane and subsequent reduction with LiAlH~4~, of the fluorinated diester obtained. Treated with phosg