## Abstract Some new fluorinated phosphoric esters are described. The rate of hydrolysis of the organic fluorine and of the phosphoric ester bond is studied. The phosphoric ester group has a stabilizing effect on the fluorine in alkaline medium, whereas the fluorine has a labilizing effect on the p
Recherches sur la formation et la transformation de dérivés organiques du fluor II. Sur la synthèse et l'estérification d'amino-alcools fluorés
✍ Scribed by Emile Cherbuliez; A. Yazgi; J. Rabinowitz
- Publisher
- John Wiley and Sons
- Year
- 1960
- Tongue
- German
- Weight
- 574 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
Abstract
The syntheses of monofluorinated amino‐alcohols (with primary, secondary and tertiary amino groups and also with quaternary ammonium groups) and of their phosphoric and acetic esters are described.
📜 SIMILAR VOLUMES
3,3‐dimethylpentane‐2,4‐diol, a new diol, and its dicarbamate have been prepared. Some N,N‐diethylcarbamates of diols have also been prepared from N,N‐diethylcarbamoyl chloride and the corresponding diols.
Some new diethylcarbamates of dialkylamino‐alcohols of type I (fluorinated or not) have been prepared from diethylcarbamylchloride and the corresponding aminoalcohols.
## Abstract The synthesis of some esters of 1‐diethylamino‐3‐fluoro‐propan‐2‐olis described. The nitrobenzoic ester is transformed with very good yield into the corresponding aminobenzoic ester by reduction with Sn and HC1 or by catalytic hydrogenation.
## Abstract Some new fluorinated hydroxy‐acids and hydroxy‐ethers as well as their phosphorylated derivatives are described.
## Abstract The synthesis of 1‐fluoro‐4,4‐di‐hydroxymethyl‐pentane (I) and its dicarbamate (II) is described. (I) is obtained by classical alkylation of methylmalonic ester with 1‐ bromo‐3‐fluoro‐propane and subsequent reduction with LiAlH~4~, of the fluorinated diester obtained. Treated with phosg