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Recherches sur la biochimie des champignons inférieurs VIII. Synthèse chimique de pigments diquinoniques

✍ Scribed by Julius Kalamar; Eric Steiner; Etienne Charollais; Théodore Posternak


Publisher
John Wiley and Sons
Year
1974
Tongue
German
Weight
640 KB
Volume
57
Category
Article
ISSN
0018-019X

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✦ Synopsis


New simplified syntheses of two natural p‐diquinonic pigments, phoenicine and oosporeine, have been described. By similar procedures, the syntheses of two other related diquinones have been carried out: 3,3′,6,6′‐tetrahydroxy‐biphenyl‐di‐p,p′‐quinone and 3,3′,6,6′‐tetrahydroxy‐4‐methyl‐biphenyl‐di‐p,p′‐quinone. The latter structure had been assigned to pyxiferine, which had been reported to be contained in the lichen Pyxine coccifera.


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Recherches sur la biochimie des champign
✍ Eric Steiner; Julius Kalamar; Etienne Charollais; Théodore Posternak 📂 Article 📅 1974 🏛 John Wiley and Sons 🌐 German ⚖ 710 KB

The biosynthesis of phoenicine and of oosporeine by intact cells of __Penicillium phoeniceum__ VAN BEYMA and of __Chaetomium aureum__ CHIVERS respectively, has been investigated. Starting from acetic acid, biosynthetic sequences have been proposed; they are based on the incorporation of radioactivit