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Recent Studies on the Reactions of Thioaldehydes and Thioketones

✍ Scribed by Kentaro Okuma


Publisher
John Wiley and Sons
Year
2003
Weight
65 KB
Volume
34
Category
Article
ISSN
0931-7597

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Studies on Reactions of Thioketones with
✍ Grzegorz Mlostoń; G. K. Surya Prakash; George A. Olah; Heinz Heimgartner 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 158 KB 👁 2 views

Treatment of 2,2,4,4-tetramethylcyclobutane-1,3-dione (6) in THF with CF 3 SiMe 3 in the presence of tetrabutylammonium fluoride (TBAF) yielded the corresponding 3-(trifluoromethyl)-3-[(trimethylsilyl)oxy]cyclobutanone 7 (Scheme 1) via nucleophilic addition of a CF À 3 anion at the CO group and subs