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Recent Results in the Catalytic Oligomerization and Co-oligomerization of Butadiene

✍ Scribed by Dr. Herbert Müller; Dr. D. Wittenberg; Dr. H. Seibt; Dr. E. Scharf

Publisher
John Wiley and Sons
Year
1965
Tongue
English
Weight
643 KB
Volume
4
Category
Article
ISSN
0044-8249

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The Catalytic Mixed Oligomerization of B
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Effects of transition metals on hydrogen
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✍ Sei Otsuka; K. Taketomi 📂 Article 📅 1966 🏛 Elsevier Science 🌐 English ⚖ 511 KB

Linear oligomerization of three deuterium isomers of butadiene (C4H6, C4H2D4, C,D6) was effected by C02(CO)s-A1Eta (I) and C0(C3H5)3, and cyclo-oligomerization of C4H6 by Ni(CO)4-AIEt3 (II) and Ni(C3Hs)2. Isotopic isomers of 3-methyl-l,4,6-heptatriene(MHT) were obtained; NMR studies indicated that o