RECENT REACTIONS OF SINGLET OXYGEN WITH HETEROCYCLIC AND AROMATIC SUBSTRATES
β Scribed by Wasserman, Harry H.
- Book ID
- 120620416
- Publisher
- John Wiley and Sons
- Year
- 1970
- Tongue
- English
- Weight
- 547 KB
- Volume
- 171
- Category
- Article
- ISSN
- 0890-6564
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π SIMILAR VOLUMES
The reactions of imidamoles with singlet oxygen are of special interest in view of the probable involvement of the imidasole system in the photooxidative inactivation of certain enzymes. Thus, loss of biological activity during photooxidation of phosphoglucomutase3, ribonuclease4 and insulin5, among
## Abstract Frontier molecular orbital theory has been applied to the [4 + 2]βcycloaddition of singlet oxygen, to monoβ and dimethylnaphthalenes and to a number of other polycyclic aromatic compounds. Semilogarithmic plots of rate constants versus second order perturbation energies are found to be