The internal rotational barriers in 2-fluorotoluene and 2-chlorotoluene are computed with the ab initio basis sets, 6-3 1 G and 6-3lG\*, as well as by single-point MP2//6-3 1G' calculations. For the fluoro derivative, good agreement with the barrier from rotational spectra is obtained. The computed
Recent orbital evolution and the internal structures of Enceladus and Dione
β Scribed by Ke Zhang; Francis Nimmo
- Publisher
- Elsevier Science
- Year
- 2009
- Tongue
- English
- Weight
- 933 KB
- Volume
- 204
- Category
- Article
- ISSN
- 0019-1035
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β¦ Synopsis
We study the orbital behavior of Saturn's satellites Enceladus and Dione during their passage through the 2:1 mean-motion resonances to constrain their interior structures, parameterized by the quantity k 2 =Q (assumed constant). Enceladus' evolution after escape from the second-order e-Enceladus e-Dione resonance requires that Γ°k 2 =Q Γ Enceladus < 8 Γ 10 Γ4 , for that Q Saturn > 18; 000. This result is in agreement with [Meyer, J., Wisdom, J., 2008b. Icarus 193, 213-223]. The present-day libration amplitude of Enceladus requires that Γ°k 2 =Q Γ Enceladus > 1:2 Γ 10 Γ4 , assuming that Q Saturn < 10 5 . Dione's present-day eccentricity indicates that Γ°k 2 =Q Γ Dione 6 3 Γ 10 Γ4 for Q Saturn > 18; 000. Assuming Maxwellian viscoelastic behavior, we find that for Enceladus a convective ice shell overlying an ocean is too dissipative to match the orbital constraints. We conclude that a conductive shell overlying an ocean is more likely, and discuss the implications of this result. Dione's ice shell is also likely to be conductive, but our results are less constraining.
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