The volume is a collection of 22 chapters written by leading experts and active researchers in the field focusing on various aspects of carbocation and onium ion chemistry. These include stable ion NMR studies, solvolytic and kinetic studies, computational work, and synthetic/preparative aspects.
Recent Developments in Carbocation and Onium Ion Chemistry
β Scribed by Kenneth K. Laali (Eds.)
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Leaves
- 538
- Series
- ACS Symposium Series 965
- Category
- Library
No coin nor oath required. For personal study only.
β¦ Synopsis
Content: Experimental and computational NMR spectroscopic investigation of silyl-substituted carbocations / Hans-Ullrich Siehl --
Super-stabilization of [pi]-conjugated cations by annelation to bicyclic frameworks / Koichi Komatsu --
Unusually stable vinyl cations / Thomas MuΜller ... [et al.] --
Vinyl iodonium salts as precursors to vinyl cations / Tadashi Okuyama and Morifumi Fujita --
Generation of alkylideneallyl cations from alkylidenecyclopropanone acetals : selectivity of reaction with nucleophiles / Morifumi Fujita and Tadashi Okuyama --
Conformational studies of cyclobutylmethyl cations / V. Prakash Reddy, G.K. Surya Prakash, and Golam Rasul --
Persistent organic cationic complexes : structure and reactivity / Gennady I. Borodkin and Vyacheslav G. Shubin --
Activation of electrophilic sites by adjacent cationic groups / Douglas A. Klumpp --
Stabilized carbocations as redox active chromophores : preparation of electrochromic materials using stabilized carbocations / Shunji Ito, Koji Akimoto, and Noboru Morita --
Cation pool method and cation flow method / Jun-ichi Yoshida --
Fluorenylidene and indenylidene dications : insights about antiaromaticity / Nancy S. Mills --
Generation, stability, and reactions of alkylated fullerene cations / Toshikazu Kitagawa --
Carbocations on surfaces : formation of bicyclobutonium cation via ionization of cyclopropylcarbinyl chloride over NaY zeolite / Marcelo Franco ... [et al.] --
MO calculations involving [mu]-hydrido cation intermediates relevant to the heptane to toluene dehydrocyclization reaction / Ted S. Sorensen and Esther C.F. Yang --
Theoretical studies on structure and dynamics of carbonium ions / Pierre M. Esteves, Felipe P. Fleming and AndreΜ G.H. Barbosa --
Quantum chemical studies of carbocations from oxidized metabolites of Aza-polycyclic aromatic hydrocarbons / Gabriela L. Borosky and Kenneth K. Laali --
How does carbocation stability control the Beckmann rearrangement reaction? / Salai C. Ammal and Hiroshi Yamataka --
Solvent effects on the chemistry of bromonium and [beta]-bromocarbenium ions as reactive intermediates / Cinzia Chiappe --
Syntheses of the CFYβ (Y = Cl, Br) and CXββΊ (X = Cl, Br, OTeFβ
) cations employing the noble-gas oxidant, XeOTeFβ
βΊSb(OTeFβ
)ββ» / HeΜleΜne P.A. Mercier, Matthew D. Moran, and Gary J. Schrobilgen --
Organoxenonium salts : synthesis by "xenodeborylation", reactivities, and NMR spectroscopic properties / H.-J. Frohn and V.V. Bardin --
Halogen transfer reactions from bis-amino halonium ions to acceptor olefins : mechanism and strategies for chiral halogenation / R. Stan Brown ... [et al.] --
Synthesis of phosphonium salts by metal-catalyzed addition reaction / Mieko Arisawa and Masahiko Yamaguchi.
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