Recent Developments in Analytical Techniques for Corrosion Research

✍ Scribed by Ihsan ulhaq Toor (editor)

• Publisher: Springer
• Year: 2022
• Tongue: English
• Leaves: 304
• Category: Library

✦ Synopsis

This book covers a wide range of advanced analytical tools, from electrochemical to in-situ/ex-situ material characterization techniques, as well as the modeling of corrosion systems to foster understanding and prediction.

When used properly, these tools can enrich our understanding of material performance (metallic materials, coatings, inhibitors) in various environments/contexts (aqueous corrosion, high-temperature corrosion). The book encourages researchers to develop new corrosion-resistant materials and supports them in devising suitable asset integrity strategies.

Offering a valuable resource for researchers, industry professionals, and graduate students alike, the book shows them how to apply these valuable analytical tools in their work.

✦ Table of Contents

Acknowledgments
Contents
Advancement in Electrochemical Techniques
Introduction
1 Introduction
1.1 Themes and Methodology for Selected Contributions
2 Advancement in Electrochemical Techniques for Coroisson Research
2.1 In-Situ Photoelectrochemcao Spectrocopy and Mott-Schottky Analysis
2.2 Voltammetry Techniques in Corrosion Research
2.3 The Utilization of Scanning Electrochemical Microscopic (SECM) Techniques in Corrosion Monitoring
2.4 Electrochemcial Impedence Spectroscopy for Monitoring the Performance of Corrosion Inhibitors
3 Advancements in Spectroscopic and Microscopic Techniques for Corrosion Research
3.1 Applications of Liquid Cell-TEM in Corrosion Research
3.2 Electrochemical Scanning Tunneling Microscopy to Study Corrosion
3.3 Recent Trends in Applications of X-ray Photoelectron Spectroscopy (XPS)
3.4 Applications of Atomic Force Microscopy in Corrosion Research
4 Advancements in Corrosion Modeling & Prediction
4.1 A Review of Erosion-Corrosion Models for the Oil and Gas Industry Applications
4.2 Effect of Hydrogen and Defects on Deformation and Failure of Austenitic Stainless Steel
4.3 Molecular Modeling for Corrosion Inhibitor Design
4.4 Hydrogen Embrittlement in Nickel-Base Superalloy
Applications of Photoelectrochemical Spectroscopy (PES) and Mott-Schottky Techniques in Corrosion Research
1 Introduction
2 Applications of Photoelectrochemical Spectroscopy and Mott-Schottky Analysis
2.1 Applications of Photoelectrochemical Spectroscopy
2.2 Applications of Mott-Schottky Analysis
3 Conclusions
References
Voltammetry and In-Situ UV–Vis Absorbance Studies for Understanding Corrosion Mechanisms
1 Introduction
2 Electrode Kinetics
2.1 Reaction Rate Constants
2.2 Mass Transport
3 Voltammetry and Electrode Reactions
3.1 Types of Voltammetry
3.2 Electrode Reactions
3.3 Surface Processes
4 Differential Pulse Voltammetry
5 Voltammetry in Corrosion Research
5.1 Evaluation of General Corrosion and Dissoltion
5.2 Evaluation of Localized Corrosion
5.3 Evaluation of Passivation and Oxide Films
5.4 Evaluation of Coating Performance
6 Photo Spectroscopy
6.1 UV–Vis Absorption Spectroscopy
6.2 Vibrational Spectroscopy
7 UV–Vis Spectroscopy in Corrosion Research
References
The Utilization of Scanning Electrochemical Microscopic (SECM) Technique in Corrosion Monitoring
1 Introduction
2 Fundamentals of SECM Technique
2.1 Basic Principle
2.2 Instrumentation
2.3 Ultra Microelectrodes
2.4 Operation Modes of SECM
3 Applications of SECM
4 Utilization of SECM on Corrosion Research
4.1 Corrosion of Metals and Alloys
4.2 Inspection on Localized Corrosion in Early Stages
4.3 Evaluation of Passive Films
4.4 Characterization of Thin Inhibitors Films
4.5 Evaluation of Degradation of Protective Coatings
5 Integration with Other Techniques
6 Future Challenges and Opportunities
7 Conclusions and Perspective
References
Electrochemical Impedance Spectroscopy: A Useful Tool for monitoring the Performance of Corrosion Inhibitors
1 Introduction
2 Basics of EIS
3 Representation of the EIS Data
4 Electrical Circuits in EIS
5 Application of EIS in the Field of Corrosion Inhibitors
5.1 Methodology Used for the Evaluation of Performance of the Corrosion Inhibitors
5.2 EIS Spectra for the Evaluation of Performance of the Corrosion Inhibitors
5.3 Evaluation of Corrosion Related Electrochemical Parameters for Examining the Performance of the Corrosion Inhibitors
5.4 Interpretation of the Data Obtained from the EIS
5.5 An Overview of the Application of EIS Data in the Evaluation of Performance of Corrosion Inhibitors
6 Limitation and Future Challenges Related to EIS
7 Conclusion
References
Advancement in Spectroscopic and Microscopic Techniques
Applications of Liquid Cell-TEM in Corrosion Research
1 Introduction to TEM and the Associated Limitations
2 Emergence of In-Situ Liquid Cell TEM
3 Limitations and Opportunities of In-Situ Liquid Cell TEM
4 In-Situ TEM Corrosion Studies
4.1 In-Situ TEM Corrosion Studies in Model Systems
4.2 In-Situ TEM Corrosion Studies in More Complex Alloys
4.3 Coupling Analytical Microscopy with Liquid Cell TEM
5 Future Directions Liquid Cell-TEM for Corrosion Studies
6 Conclusion
References
Applications of Electrochemical Scanning Tunneling Microscopy in Corrosion Research
1 Scanning Tunneling Microscopy
1.1 History of Scanning Tunneling Microscopy
1.2 Working Mechanism of STM
1.3 Scanning Modes of STM
1.4 Electrochemical Scanning Tunneling Microscopy (ECSTM)
1.5 ECSTM Working Mechanism
1.6 Application of ECSTM to Corrosion
References
Recent Trends in Applications of X-ray Photoelectron Spectroscopy (XPS) Technique in Coatings for Corrosion Protection
1 Introduction
2 Analysis of Nanocomposite Coatings for Corrosion Protection
3 Characterization of Nanocarriers
4 Post Corrosion Analysis of Substrates Using XPS
5 Current Limitations
6 Conclusions and Future Outlook
References
Applications of Atomic Force Microscopy in Corrosion Research
1 Introduction
2 Working Principle of AFM
3 Imaging Modes of AFM
4 Development of AFM Technology
5 Uses of AFM in Corrosion Research
References
Advancement in Corrosion Modeling and Prediction
A Review of Erosion-Corrosion Models for the Oil and Gas Industry Applications
1 Introduction
2 Solid Particles Erosion
2.1 Erosion Modeling
3 CO2 Corrosion
3.1 CO2 Corrosion Modeling
4 Erosion-Corrosion
4.1 Erosion-Corrosion Modeling
4.2 Erosion-Corrosion Inhibition
4.3 Inhibited Erosion-Corrosion Modeling
5 Conclusion
References
Effect of Hydrogen and Defects on Deformation and Failure of Austenitic Stainless Steel
1 Introduction
2 Crystal Plasticity Model with Hydrogen Effects
2.1 Crystal Plasticity Theory
2.2 Incorporation of Hydrogen Effects
3 Methodology
4 Results and Discussion
4.1 Effect of Intial Crystal Orientation and Hydrogen on Equivalent Stress
4.2 Effect of Intial Crystal Orientation and Hydrogen on Void Growth
4.3 Effect of Initial Crystal Orientation on Hydrogen in Traps Distribution During Deformation
4.4 Hydrogen in Traps and Slip Activity During Deformation for Different Initial Orientations
4.5 Crystal Orientation Evolution in the Presence of Hydrogen
5 Conclusions
6 Future Challenges and Opportunities
References
Molecular Modeling for Corrosion Inhibitor Design
1 Introduction
2 Theory of Molecular Dynamics Simulation
2.1 Ensembles
2.2 Force Fields
2.3 Periodic Boundary Conditions
3 Application of MD Simulations to Corrosion Inhibitor Design
3.1 Corrosion Inhibition of Steel
3.2 Corrosion Inhibition of Copper
3.3 Corrosion Inhibition of Aluminum
4 Current Limitations and Future Opportunities
5 Conclusion
References
Hydrogen Embrittlement in Nickel-Base Superalloy 718
1 Introduction
2 Microstructure of Ni-Base Superalloys
3 Microstructure-Property Relationship of H-charged Ni-Base Superalloys
4 Hydrogen Embrittlement Mechanisms in Alloy 718
4.1 Hydrogen Enhanced Localized Plasticity (HELP)
4.2 Hydrogen Enhanced Decohesion (HEDE)
5 Conclusions
References