Recent approaches towards the asymmetric synthesis of ?,?-disubstituted ?-amino acids
β Scribed by Vogt, Henning; Br?se, Stefan
- Book ID
- 115531738
- Publisher
- Royal Society of Chemistry
- Year
- 2007
- Tongue
- English
- Weight
- 869 KB
- Volume
- 5
- Category
- Article
- ISSN
- 1477-0520
- DOI
- 10.1039/b611091f
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π SIMILAR VOLUMES
Copper(salen) complex 1 has been found to catalyse the asymmetric alkylation of enolates derived from a variety of amino acids. There is a clear relationship between the size of the side chain in the substrate and the enantioselectivity of the process, so that the enantioselectivity decreases in the
## Abstract For Abstract see ChemInform Abstract in Full Text.
In an earlier communloatlon 1) , aaymmetrlc alkylatlon of cyclohexanone enamine wae described. Thle paper deale with an extenelon of thle reaction to the aldehyde enamlne. mamine alkylatlon was devleed by stork and hle co-workers 8)