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Recent Advances of Mechanistic Studies on Asymmetric Hydrogenation of Dehydroamino Acid Derivatives Catalyzed by Diphosphine—Rh and —Ru Complexes

✍ Scribed by Masaki Tsukamoto; Masato Kitamura

Publisher
John Wiley and Sons
Year
2006
Weight
8 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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Asymmetric Transfer Hydrogenation of Ketones Catalyzed by Amino Acid Derived Rhodium Complexes: On the Origin of Enantioselectivity and Enantioswitchability
✍ Katrin Ahlford; Jesper Ekström; Alexey B. Zaitsev; Per Ryberg; Lars Eriksson; Ha 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 484 KB 👁 2 views

## Abstract Amino acid based thioamides, hydroxamic acids, and hydrazides have been evaluated as ligands in the rhodium‐catalyzed asymmetric transfer hydrogenation of ketones in 2‐propanol. Catalysts containing thioamide ligands derived from L‐valine were found to selectively generate the product w