𝔖 Bobbio Scriptorium
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Recent advances of intermolecular Diels-Alder reaction in bio-inspired synthesis of natural products

✍ Scribed by Wan, ChunYun; Deng, Jun; Liu, Hua; Bian, Ming; Li, Ang


Book ID
125371875
Publisher
SP Science China Press
Year
2014
Tongue
English
Weight
981 KB
Volume
57
Category
Article
ISSN
1674-7291

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Intramolecular Diels–Alder reaction lead
✍ Junichi Shiina; Shigeru Nishiyama 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 176 KB

Tricyclic compounds 4a and 4b possessing a bicyclo[4.3.0] moiety, were successfully synthesized by using the intramolecular Diels -Alder reaction. The siloxy-rather than acyloxy-substituents increased the ratio of the endo-cylcoadducts 10 and 12. The oxygen substitution of 9 influenced conformation