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Recent advances in the chemistry of well-defined olefin and acetylene metathesis catalysts

✍ Scribed by Richard R. Schrock; John H. Freudenberger; Mark L. Listemann; Laughlin G. McCullough


Publisher
Elsevier Science
Year
1985
Weight
503 KB
Volume
28
Category
Article
ISSN
0304-5102

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An overview of the recent synthetic breakthroughs brought about by the discovery of new, functional group tolerant late transition metal (Rh and Ru)-based catalysts is proposed. Whereas dirhodium(II)-based complexes promote only carbene transfer reactions to olefins (i.e. olefin cyclopropanation), a