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Recent Advances in Organic Reactions Catalyzed by Lanthanide (III) Complexes

✍ Scribed by Chen Rui-Fang; Qian Chang-Tao


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
814 KB
Volume
20
Category
Article
ISSN
0256-7660

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✦ Synopsis


Abstract

Lanthanide compounds have been attracting much attention in organic synthesis. Chiral Ln‐substituted BINOL have been widely studied in several asymmetric organic reactions. LnCl~3~ and Ln(OTf)~3~ have been expected to serve as Lewis acids and have been applied to many important synthetic reactions in a one‐pot manner. Ln(O‐i‐Pr)~3~ exhibits some basic characters, which also can be utilized in some special organic transformation. This article deals with some lanthanides(III) complexes promoted organic reactions, which we have recently developed.


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