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Rearrangements of the 2,6-diaryl-3,7-dioxabicyclo[3.3.0] octane skeleton, part III. Reaction of gmelinol with BF3-etherate and N,N-dimethylaniline

✍ Scribed by Robert S. Ward; Andrew Pelter; Revuru Venkateswarlu; Chakicherla Kamakshi; Ayalasomayajula Lakshmi


Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
407 KB
Volume
52
Category
Article
ISSN
0040-4020

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An Alternative Diastereospecific Approach to (Β±)-Samin and 2,6-Diaryl-3,7-dioxabicyclo[3.3.0]octane [Furanofuran] Lignans Based on the Ireland-Claisen Rearrangement of Unsaturated Oxa-macrolides. -Ireland-Claisen rearrangement of the macrolide (II) gives stereospecifically the tetrahydrofurancarbox