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Rearrangements of Polyynes. VII. 1 Formation of Allenes

โœ Scribed by Ford, J. H.; Thompson, C. D.; Marvel, C. S.


Book ID
127065566
Publisher
American Chemical Society
Year
1935
Tongue
English
Weight
535 KB
Volume
57
Category
Article
ISSN
0002-7863

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Synthesis and claisen rearrangement of 1
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A number of ally1 allenyl ethers (1) have been synthesised and shown to undergo the Claisen rearrangement. The kinetics of rearrangement of (lb) together with stereochemical data obtained, is consistent with a concerted mechanism for these rearrangements. A number of variants of the Claisen rearra