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Rearrangements of N-acyl-2-aza-1,5-hexadienes: application to synthesis of traechelanthamidine and supinidine

✍ Scribed by David J. Hart; Teng-Kuei Yang

Publisher: Elsevier Science
Year: 1982
Tongue: French
Weight: 204 KB
Volume: 23
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)87451-1

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✦ Synopsis

Efficient syntheses of the pyrrolizidine bases traechelanthamldlne (4) and supinldine (2) via an N-acyllminlum ion rearrangement-cycllzatlon are described.

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