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Rearrangements of ledene and aromadendrene in superacids

โœ Scribed by Marina P. Polovinka; Andrei A. Shal'ko; Dina V. Korchagina; Yurii V. Gatilov; Vladimir V. Shcherbukhin; Vladimir A. Barkhash

Book ID
103410177
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
126 KB
Volume
37
Category
Article
ISSN
0040-4039

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โœ F.Javier Moreno-Dorado; Yvonne M.A.W Lamers; Grigore Mironov; Joannes B.P.A Wijn ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 237 KB

The chemistry of (รพ)-ledene and (2)-isoledene, both easily available from (รพ)-aromadendrene has been investigated. Reactions at the double bond of ledene take place preferably from the b-side. Under acidic conditions its C7 -C8 b-epoxide and b-diol preferably react via carbocations, which are initia