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Rearrangements of Aryl Sulfones. IV. Substituted Phenyl Mesityl Sulfones 1

โœ Scribed by TRUCE, WILLIAM E.; GUY, MARY M.


Book ID
127365442
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
818 KB
Volume
26
Category
Article
ISSN
0022-3263

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Substituted thiophenyl ally1 sulfones undergo a 1,3-allylic sulfonyl shift and this rearrangement has been utilized within a metallation-alkylation sequence. The synthetic application of sulfones to the preparation of natural products has increased enormously during the past several years. 1~ This