Rearrangements of 1-Phenyl-1,2,3-Triazoles Bearing a Hydrazone or Oxime Function at the 4-Position
✍ Scribed by Gerrit L'abbé; Gonda van Essche; Pieter Delbeke; Suzanne Toppet
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 97 KB
- Volume
- 99
- Category
- Article
- ISSN
- 0037-9646
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## Abstract The synthesis of a series of zinc phthalocyanines partially phenyl‐substituted at the 1‐, 4‐, 8‐, 11‐, 15‐, 18‐, 22‐, and/or 25‐positions (the so‐called α‐positions) is reported. Macrocycle formation based on 3,6‐diphenylphthalonitrile, __o__‐phthalonitrile, and zinc acetate predominant
A density functional computational study shows that 4-nitro-1,2,3-triazole, which is highly impact sensitive, can decompose through ring opening and subsequent N 2 evolution, with the net release of 12 kcalrmol. An input of 52 kcalrmol is required to initiate the process. ᮊ 1997 John Wiley & Sons, I