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Rearrangements in the formation of pyrazolines from alkyl hydrazines and unsaturated carbonyl compounds

✍ Scribed by B. V. Ioffe; V. V. Tsibul'skii


Book ID
112329289
Publisher
Springer US
Year
1972
Tongue
English
Weight
317 KB
Volume
5
Category
Article
ISSN
0009-3122

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Y-alkylation of lithium dienolates deriv
✍ Amos B. Smith III; Robert M. Scarborough Jr. πŸ“‚ Article πŸ“… 1978 πŸ› Elsevier Science 🌐 French βš– 242 KB

Although it is now generally accepted that lithium dienolates undergo near exclusive alkylation at the a rather than the y carbon, 1 we will demonstrate in this letter that, at least, for some 8-alkoxy-a,@-unsaturated carbonyl compounds, subtle structural features can markedly effect the a-selectivi