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Rearrangements accompanying the fragmentation of ionized 1-phenylalkan-1-ols

✍ Scribed by H. Budzikiewicz; G. Drabner; Ch. Hammes

Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
310 KB
Volume
28
Category
Article
ISSN
1076-5174

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✦ Synopsis

Some aspects of the fragmentation sequence of 1-phenylalkan-1-01s (C,H,CH(OH)R), which consists of the loss of R' followed by the elimination of CO and subsequently of H , , are discussed. Labelling studies and collision activation data of reference compounds allow a mechanism to be proposed for this rearrangement.

πŸ“œ SIMILAR VOLUMES

The fragmentation of 1-phenyl-2-propen-1
The fragmentation of 1-phenyl-2-propen-1-ol under electron impact
✍ Jean-Pierre Denhez; Madeleine Corval; Pierre Dizabo πŸ“‚ Article πŸ“… 1981 πŸ› John Wiley and Sons 🌐 English βš– 409 KB

## Abstract The electron impact mass spectra of 1‐phenyl‐2‐propen‐1‐ol and its specifically deuterated analogues have been investigated. Most of the decomposition pathways involve skeletal rearrangements or hydrogen atom transfers, such that a rearrangement of the excited molecular ions of 1‐phenyl