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Rearrangement reactions of bicyclic systems. Part V. 1 Acid-catalysed rearrangements of 1,4-dihydro-1,5,8-trimethoxy-1,4-ethenonaphthalene and the remarkable effect of aromatic methoxy-groups on the course of the reaction

โœ Scribed by Neil J. Hales; Harry Heaney; John H. Hollinshead; Ram P. Sharma


Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
535 KB
Volume
51
Category
Article
ISSN
0040-4020

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## Abstract The thermal conversion of 1โ€phenylโ€1โ€butenโ€3โ€yne (1) into the cycloisomerization products naphthalene (2), azulene (3), and 1โ€methyleneโ€1__H__โ€indene (4) has been studied at temperatures between 550 and 1000ยฐC, a reaction time of approximately 0.3 s at 13 Torr (FVP) and at low partial p