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Rearrangement reactions of aromadendrane derivatives. The synthesis of (+)-maaliol, starting from natural (+)-aromadendrene-IV

✍ Scribed by Harrie J.M. Gijsen; Joannes B.P.A. Wijnberg; Connie van Ravenswaay; Aede de Groot


Book ID
104203082
Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
991 KB
Volume
50
Category
Article
ISSN
0040-4020

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Thermal rearrangement of bicyclogermacra
✍ Harrie J.M. Gijsen; Joannes B.P.A. Wijnberg; Aede de Groot πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 French βš– 800 KB

## Treatment of a distillation tail of Eucalyptus globulus, containing mainly (+)-aromadendrene (1) and (-)-alloaromadendrene (Z), with K/Al203 gives a quantitative conversion of 1 anti 2 into isoledene (4). Oxidative cleavage of the central double bond in 4 produces (+)-bicyclogermacrane-l,Sdione (