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Rearrangement of tetramethylthiourea to dimethyldithiocarbamate and crystal structures of [Tc(O)(C5H12N2S)2((CH3)2NCSS)](PF6)2 and [Tc(DPPE)2((CH3)2NCSS)](PF6)

✍ Scribed by Fernande D. Rochon; Robert Melanson; Pi-Chang Kong


Book ID
108328145
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
764 KB
Volume
194
Category
Article
ISSN
0020-1693

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The title compound and its potassium analog have been prepared from corresponding aqueous solutions of 9 T c 0 , at p H z 2 with SO2 as a reducing agent. An X-ray structure determination of the Na-salt showed Tc coordinated to the tetradentate N (CH,COO)Z-ligand (NTA). Two Tc-NTA moieties are joined