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Rearrangement of an Ammonium Ylide: Mechanisms and Kinetic Parameters

โœ Scribed by Bonneau, Roland; Reuter, Ingmar; Liu, Michael T. H.


Book ID
127210521
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
244 KB
Volume
116
Category
Article
ISSN
0002-7863

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Mechanism of the Stevens Rearrangement of Ammonium Ylides. -The title rearrangement of the ylide precursor (I) is studied, revealing that the Stevens rearrangement occurs at room temperature. The isomerization to compound (II) is always accompanied by formation of the Sommelet-Hauser rearrangement p