The addition of an acetyl radical on caryophyllene leads to formation of the four isomeric ketones 5-8 involving a novel rearrangement of the caryophyllene skeleton. The acid catalyzed rearrangement of caryophyllene 1 has been studied in detail'. The final re-\_ action products are clovene 2, caryo
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Rearrangement of a Cyclohexyl Radical to a Cyclopentylmethyl Radical on the Avermectin Skeleton
โ Scribed by Kessabi, Fiona Murphy; Winkler, Tammo; Luft, Jennifer A. R.; Houk, K. N.
- Book ID
- 120391391
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 120 KB
- Volume
- 10
- Category
- Article
- ISSN
- 1523-7060
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