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Rearrangement of 5-Azido-1,2,3-Triazoles: Conjugation effect of the N-1 Substituent

✍ Scribed by Gerrit L'abbé; Gonda Van Essche; Wim Meutermans


Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
107 KB
Volume
99
Category
Article
ISSN
0037-9646

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Correlation analysis of the oxidation potentials of a series of N,N',N@-triphenyl-1,3,5-triaminobenzenes (TPABs) substituted at the para positions of the outer phenyl rings shows a linear free energy relationship with resonance-enhanced substituent parameters (s ). Reaction parameters (r ) for oxida