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REARRANGEMENT AND FRAGMENTATION REACTIONS IN CARBENOID DECOMPOSITION OF DIAZO HYDROCARBONS

✍ Scribed by Friedman, L.; Shechter, H.

Book ID: 127138604
Publisher: American Chemical Society
Year: 1960
Tongue: English
Weight: 275 KB
Volume: 82
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja01489a063

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## Abstract The rearrangements of 4′‐methoxy‐__N__‐methyl‐ and __N__‐methyl‐4′‐nitro‐diatzoaminobenzene have been studied in 20% acetonitrile/aqueous buffers. The reactions are specifically acid catalyzed and involve pre‐equilibrium formation of amine and diazonium salt followed by rate‐limiting at