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Rearrangement and dissociative processes in the [H2, C, O].cntdot.+ energy surface: an example of nonergodic behavior

✍ Scribed by Bouma, Willem J.; Burgers, Peter C.; Holmes, John L.; Radom, Leo.


Book ID
126161549
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
487 KB
Volume
108
Category
Article
ISSN
0002-7863

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The rotational cutoff levels of C,( B' 'Z:, u" = 1,2), produced in the multiphoton dissociation of jet-cooled acetylene at 193 nm, have been measured using laser-induced fluorescence. This data is used to calculate the values AHf,,(C2) = 194.8iO.5 kcal/ mol and D,(CC-H) = 112.0 kO.8 kcal/mol, in exc