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Real-time X-ray scattering study during the thermal conversion of a precursor polymer to poly(p-phenylene vinylene)

✍ Scribed by T.A. Ezquerra; E. Lopez-Cabarcos; F.J. Baltà-Calleja; J.D. Stenger-Smith; R.W. Lenz


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
408 KB
Volume
32
Category
Article
ISSN
0032-3861

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This paper reports the thermal conversion of the tetrahydrothiophene (THT)-precursor to poly(p-phenylene vinylene) (PPV). Detailed investigations of the conversion process show that the leaving groups THT and HCl do not eliminate simultaneously. Moderate temperatures ( 125 °C) are sufficient to elim