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Real-time femtosecond probing of ‘‘transition states’’ in chemical reactions

✍ Scribed by Dantus, Marcos; Rosker, Mark J.; Zewail, Ahmed H.


Book ID
120449688
Publisher
American Institute of Physics
Year
1987
Tongue
English
Weight
577 KB
Volume
87
Category
Article
ISSN
0021-9606

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Femtosecond real-time alignment in chemi
✍ M. Dantus; R.M. Bowman; J.S. Baskin; A.H. Zewail 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 576 KB

Femtosecond real-time alignment in dissociation reactions is observed experimentally for HgI2 and ICN. The results are accounted for by the classical theory outlined here. This study adds a new dimension to femtosecond transition-state spectroscopy (ITS), namely the probing of the "vector dynamics"