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Reactivity Studies on Fe III −(O 22- )−Cu II Compounds: Influence of the Ligand Architecture and Copper Ligand Denticity

✍ Scribed by Chufán, Eduardo E.; Mondal, Biplab; Gandhi, Thirumanavelan; Kim, Eunsuk; Rubie, Nick D.; Moënne-Loccoz, Pierre; Karlin, Kenneth D.


Book ID
127378383
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
406 KB
Volume
46
Category
Article
ISSN
0020-1669

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## Abstract The synthesis and crystal structures of three nonheme diiron(III) complexes with a tridentate N,N,O Schiff‐baseligand, 2‐({[2‐(dimethylamino)ethyl]imino}methyl)phenol (HL), are reported. Complexes [Fe~2~OL~2~(NCO)~2~] (1a) and [Fe~2~OL~2~(SAL)~2~]·H~2~O [SAL = __o__‐(CHO)C~6~H~4~O^–^] (