Reactivity studies of organic substances towards hydroxyl radicals under atmospheric conditions
β Scribed by I. Barnes; V. Bastian; K.H. Becker; E.H. Fink; F. Zabel
- Book ID
- 113121444
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 590 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0004-6981
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π SIMILAR VOLUMES
A flow system has been developed to study relative rate coefficients of hydroxyl radicals reacting with alkanes under conditions relating to tropospheric chemistry. Relative Arrhenius parameters have been measured over the temperature range 243-328 K for pairs of alkanes from a list consisting of n-
The rate constant for the gas-phase reaction of the hydroxyl radical with trifluoroacetic acid has been determined over the temperature range 283-323 K using a relative rate technique. The results provide a value of k( OH+CF,C(O)OH) = 2.O~lO-\*~exp(-l46~500/T)cm~molecule~'s-'basedonk(OH+C~H,)=7.8~lO