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Reactivity of α,β-unsaturated carbonyl compounds towards nucleophilic addition reaction: a local hard–soft acid–base approach

✍ Scribed by Mondal, Paritosh; Hazarika, Kalyan Kr.; Deka, Ramesh Ch.


Book ID
120199945
Publisher
Royal Society of Chemistry
Year
2003
Tongue
English
Weight
94 KB
Volume
6
Category
Article
ISSN
1460-2733

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Formation of a reasonably stabilized tri
✍ Tatsuya Shono; Manabu Ishifune; Osamu Ishige; Hiroshi Uyama; Shigenori Kashimura 📂 Article 📅 1990 🏛 Elsevier Science 🌐 French ⚖ 260 KB

A reasonably stabilized trichloromethyl anion (TCMA) was formed by the reaction of chloroform with an electrogenerated base prepared by the electroreduction of Zpyrrolidone, and the addition of this TCIvIA to a$unsaturated esters gave the corresponding B-trichloromethyl esters in good yields.